Although not super accurate, assuming the main tank is 92 gallons, measure its length and them measure the length of the aux tank. Approximations will be close enough. Take the ratio of the aux tank length to the main tank length and multiply that by 92. That will be a rough estimate of the aux capacity ( This calculation assumes that both tanks are the same width, depth and shape).
A more accurate approach is of course to run off AUX till it is empty, switch to main and get to the fuel dock to fill up the aux tank. That is going to be panful in the wallet.